Benedict Arnold was a general during the American Revolutionary War.
When Fat Tony was speaking to Homer, who he believed was Krusty, Homer told them that he was Benedict Arnold. Legs asked Homer if he is the same Benedict Arnold who plotted to surrender West Point to the hated British.
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Benedict Arnold was in the Jury of the Damned picked by Flanders the Devil after Homer sold his soul to him. When Marge showed a photo to the jury, Blackbeard looked at it before Arnold took it from him. He read the back on the photo, where Homer had written that Marge owned his soul.